The function to automatically library search peaks is not switched on by default. With PostRun closed, in the C: Drive > GCMSSolutions > Regist please double click the file "AutoSpcTableLibSearch_ON":
Then ensure that within PostRun when you right click on the chromatogram, that either 'Compound Name in Spectrum Proc. Table' or 'Name' is ticked to display the top library search above each peak:
(GCMS) Automatic Library Search in GCMSSolution PostRun - Registry File Toggle
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